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In the paper industry, foam is a persistent issue that affects production efficiency and product quality. Whether in pulping, papermaking, or coating processes, foam formation can lead to surface defects in paper, unstable equipment operation, and even energy waste. Therefore, the application of defoamers has become a key technology to address this challenge. This article explores the causes of foam in the paper industry, the working mechanisms of defoamers, and their practical applications.
Foam in papermaking primarily results from the following factors:
Mechanical agitation: High-speed mixing and pumping during pulping, bleaching, and papermaking introduce air, forming foam.
Chemical additives: Surfactants such as dispersants, sizing agents, and wet-strength agents reduce surface tension, stabilizing foam.
Natural components: Resins and fatty acids released from wood during pulping further aggravate foam issues.
The hazards of foam cannot be ignored:
Reduced paper quality: Foam causes pinholes, voids, and uneven surfaces in paper.
Lower production efficiency: Foam occupies equipment space, disrupts pulp flow, and may even lead to overflow shutdowns.
Increased energy consumption: Foam complicates pumping and dewatering, raising energy costs.
Defoamers eliminate and suppress foam by destabilizing its structure. Their mechanisms include:
Reducing surface tension: Defoamer molecules have low surface tension, allowing them to penetrate and rupture foam films.
Breaking foam structure: Hydrophobic particles (e.g., silica) in defoamers puncture foam films, accelerating collapse.
Preventing foam recurrence: Some high-efficiency defoamers form a protective layer on liquid surfaces, inhibiting new foam formation.
Different papermaking processes require specific defoamers:
Features: Fast foam knockdown, long-lasting suppression, suitable for high-shear environments.
Applications: Widely used in pulping, papermaking, and wastewater treatment.
Features: Cost-effective, suitable for low-to-medium foam systems.
Applications: Commonly used in recycled pulp processing and coating stages.
Features: Heat-resistant, alkali-stable, ideal for high-temperature bleaching and chemical recovery.
Applications: Mainly used in chemical pulping and bleaching processes.
Features: Combine multiple defoaming agents for broad adaptability.
Applications: Suitable for complex foam control scenarios.
Pulping stage: Defoamers minimize foam impact on pulp uniformity during refining and bleaching.
Papermaking stage: Applied in the wire, press, and dryer sections to prevent paper defects.
Coating stage: Prevent foam in coatings to ensure uniform application.
Wastewater treatment: Reduce foam interference in sedimentation and filtration, improving efficiency.
With tightening environmental regulations, defoamers are evolving toward high efficiency, low toxicity, and biodegradability. Innovations like nano-defoamers and bio-based defoamers will offer greener and more effective solutions for the paper industry.
Defoamers play a crucial role in resolving foam-related challenges, enhancing paper quality, and optimizing production efficiency. Selecting the right defoamer and optimizing its usage are vital for cost reduction and performance improvement. As technology advances, defoamers will continue to be an indispensable asset in the paper industry.